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Investigation of Inhibition Effect of 1-(aminoN-phenyl methanethio) thiosemicarbazide on Carbon Steel Corrosion in Acidic Solution: Adsorption Behavior Study using Fast Fourier Transform Continuous Cyclic Voltammetry
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نویسنده
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Shahabi Shirin ,Norouzi Parviz ,Ganjali Reza Mohammad
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منبع
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analytical and bioanalytical electrochemistry - 2014 - دوره : 6 - شماره : 3 - صفحه:260 -272
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چکیده
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Corrosion inhibition of carbon steel in 1.0 m hcl solution by 1-(aminonphenylmethanethio)thiosemicarbazide (aptsc) was investigated by potentiodynamicpolarization, electrochemical impedance spectroscopy (eis) and fast fourier transformcontinuous cyclic voltammetry (fftccv). polarization studies revealed that aptsc is amixed-type corrosion inhibitor. the results showed that the inhibition efficiency increasedwith increasing the inhibitor concentration and maximum inhibition was obtained 92% at1.0×10?3 m of aptsc. eis results confirmed that the inhibitor is adsorbed on the carbonsteel surface, leading to increase the polarization resistance (rp) and decrease the doublelayer capacitance. fftccv confirmed that the addition of inhibitor into the hcl solutiondecreased the rate of carbon steel corrosion. also, it was found that after about 3400 s, theinhibitor reaches to its maximum surface coverage
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کلیدواژه
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Carbon steel ,Corrosion inhibitor ,Adsorption ,FFTCCV
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آدرس
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university of tehran, Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran, ایران, university of tehran, Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran, ایران, university of tehran, Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran, ایران
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Authors
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