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Construction of Chromium Potentiometric Sensor by using N-banzoyl-N′(6-methyl-2-pyridyl) thiourea as an Excellent Ionophore
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نویسنده
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Hajiaghababaei Leila ,Mohamadi Neda ,Adhami Forogh
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منبع
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analytical and bioanalytical electrochemistry - 2014 - دوره : 6 - شماره : 5 - صفحه:583 -594
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چکیده
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Ion potentiometric sensors are playing an important role in environmental analysisbecause of their simplicity and rapidity. in this study, a potentiometric liquid membranesensor for simple and fast quantification of chromium in various samples was made. nbanzoyl-n?(6-methyl-2-pyridyl) thiourea was selected as a sensing material in the organicphase of the pvc membrane. the wide linear range (10-6-10-1 mol l-1), low detection limit(3.0×10-7 mol l-1), and fast response time (~5 s) are the characterizations of thiselectrochemical sensor. the effects of some factors such as internal solution, ph, life timeand selectivity were investigated. finally, it was used for direct determination of chromiumand as an indicator electrode in potentiometric titration of chromium ion
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کلیدواژه
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Potentiometric sensor ,Liquid membrane ,Chromium ,Tea and cocoa samples
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آدرس
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islamic azad university, Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran, ایران, islamic azad university, Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran, ایران, islamic azad university, Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran, ایران
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Authors
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