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   Electrochemical Investigation of 4-Aminophenol at CTAB Modified Carbon Paste Electrode: A Cyclic Voltammetric Technique  
   
نویسنده Chandrashekar N. Bannanakere ,Kumara Swamy E. Bahaddurghatta ,Pandurangachar Mundargi ,Sathisha V. Tammanekar ,Sherigara S. Bailure
منبع analytical and bioanalytical electrochemistry - 2011 - دوره : 3 - شماره : 3 - صفحه:224 -232
چکیده    4-aminophenol is the main impurity present in preparations of paracetamol.using the cyclic voltammetry, the electrode behaviour of 4-aminophenol has been studiedin 0.1 m phosphate buffer solutions at carbon paste electrode and surfactant modifiedcarbon paste electrode. the optimal potential window of wide range from -0.4 v to 0.7 vwas selected. the electron transfer kinetics of the ctab/cpe in the detection of analytewas determined by the scan rate effect and concentration variation studies. the scan rateeffect showed the electrode process is adsorption controlled. the oxidation peak currentsrepresented a linear dependence on 4-aminophenol concentration from 1 mm to 4 mmwith correlation coefficient r2=0.9942. the effect of cationic surfactant shows good highsensitivity and stability for the redox process of the 4-amino phenol. the detection limitwas found to be 1×10-7 m.
کلیدواژه 4-aminophenol ,CTAB Modified Carbon Paste Electrode ,PBS ,Cyclic Voltammetry
آدرس Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Shankaraghatta -577 451, Shimoga, Karnataka, India, India, Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Shankaraghatta -577 451, Shimoga, Karnataka, India, India, Department of Chemistry, SSMRV Degree College, Jayanagara 4T Block, Banglore-41, Karnataka, India , India , Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Shankaraghatta -577 451, Shimoga, Karnataka, India, India, Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Shankaraghatta -577 451, Shimoga, Karnataka, India, India
 
     
   
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