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Effect of L-Arginine on Electrical Conductances of Aqueous Ionic Liquids 1-Alkyl-3-methylimidazolium Bromide Solutions at T = 298.15 K
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نویسنده
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Shekaari Hemayat ,Jebali Fatemeh ,Mousavi S. Sedighehnaz
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منبع
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analytical and bioanalytical electrochemistry - 2010 - دوره : 2 - شماره : 2 - صفحه:79 -87
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چکیده
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Electrical conductances of aqueous ionic liquids, 1-propyl-3-methylimidazoliumbromide, 1-butyl-3-methylimidazolium bromide, 1-pentyl-3-methylimidazolium bromide,1-hexyl-3-methylimidazolium bromide solutions in dilute region in the presence of aminoacid, l-arginine, have been measured at t = 298.15 k. the ion association constants, ka,limiting molar conductivities, 0? and distance parameters, r were obtained using lowconcentration chemical model (lccm) conductivity equation for the investigated ionicliquids. the results show that the ka value and limiting molar conductivity, ?0 decrease withincreasing l-arginine concentration and lengthening alkyl chain of ionic liquids. therefore,there is slight ion association effect in [hmim]br. this can be attributed to the interaction of[rmim]br with the amino acids and increasing viscosity of mixture.
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کلیدواژه
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Electrical conductance ,Ionic liquids ,L-arginine ,Ion association constant
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آدرس
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university of mohaghegh ardabili, ایران, university of mohaghegh ardabili, ایران, university of mohaghegh ardabili, ایران
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Authors
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