α-C2SH synthesis in the mixtures with CaO/SiO2=1.5 and application as a precursor for binder material

The parameters of α-c2sh hydrothermal synthesis (4-72 h; 200°c) from a non-stoichiometric composition (cao/sic>2 = 1.5) of cao and si02.nh2 0 mixture were determined, and a sequence of intermediary compound formation was examined and explained. it was estimated that in the synthesis products, α-c2sh dominates at 200°c after 8 to 24 h. when duration of hydrothermal treatment was shorter - c-s-h(i) and cs- h(ii), as longer - kilchoanite, prevail in the products. also, the hydration and strength properties of the binder material created on α-c2sh basis were determined. the binder material was prepared by mixing α-c2sh and quartz sand (1:1 by mass). later on, sample was ground at 950 rpm for 4 min and burned at 450° c for 30 min under air atmosphere. it was determined that calorimetric curve of created binder material differs from the one of ordinary cements as it involves only the three exothermic reactions and the amount of total cumulative heat grows with the increasing hydration time. as expected, the tendency of strength increment was observed after 7-28 days of hardening: compressive strength increased to 15.5 and 24.0 mpa, respectively. the products of synthesis and hardening were characterized by xrd, ft-ir, and sta analyses.