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   Removal of Novacron black dye from aqueous solutions using low cost agricultural waste: Batch and fixed bed study  
   
نویسنده Nawaz S. ,Bhatti H.N. ,Bokhari T.H. ,Sadaf S.
منبع scientia iranica - 2014 - دوره : 21 - شماره : 6-C2 - صفحه:2066 -2075
چکیده    The present study deals with the removal of novacron black dye with peanut peels biomass, a low cost agricultural waste. the batch mode experiments were performed to compare the biosorption potential of selected biosorbent in its native, glutaraldehydetreated and immobilized form. experiments were conducted as a function of ph, biosorbent dose, contact time, initial dye concentration and temperature. glutaraldehyde-treated biomass exhibited better biosorption capacity as compared to the native and immobilized peanut peels. maximum biosorption capacity (37.1 mg/g) of novacron black dye by peanut peels was observed at ph 2 using 0.05 g biosorbent. equilibrium data were analyzed by langmuir, freundlich and temkin isotherm models. langmuir isotherm model fitted very well to the equilibrium data. the kinetic data was modeled using pseudo-first-order, pseudo-second-order and intra-particle diffusion models. negative values of ∆g° depicted the spontaneous nature of biosorption process. column studies were performed to optimize the bed height, ow rate and initial dye concentration. the results revealed that the best biosorption was achieved at greater bed heights, lower ow rates and higher initial dye concentrations. bohrat-adams model fitted very well to the column data of novacron black dye biosorption onto peanut peels biomass.
کلیدواژه Biosorption; Novacron black; Thermodynamics; Kinetic modeling; Bohrat-Adams model
آدرس Government College University, Department of Chemistry, Pakistan, University of Agriculture, Department of Chemistry, Environmental Chemistry Laboratory, Pakistan, Government College University, Department of Chemistry, Pakistan, University of Agriculture, Department of Chemistry, Environmental Chemistry Laboratory, Pakistan
 
     
   
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