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two luminescent cadmium(ii) coordination compounds based on tetrazole–carboxylates
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نویسنده
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hao xinyu ,li yan ,ren jing’ao ,shi conghao ,liu yuanhui ,li qiaoyun ,zou dengfeng ,yang gaowen
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منبع
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journal of the iranian chemical society - 2020 - دوره : 17 - شماره : 11 - صفحه:2981 -2986
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چکیده
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Tetrazole–carboxylate ligands are excellent building blocks to construct novel coordination architectures. 5-aminotetrazole-1-isopropionic acid (hatzipa) and 3,3-di(1h-tetrazol-5-yl)pentanedioic acid (h4dtzpda) were prepared. and reactions of the two ligands with cdcl2·2.5h2o afforded [cd(atzipa)2(h2o)(etoh)] (1) and [cd2(h2dtzpda)2(h2o)3]·3h2o (2), respectively. compound 1 shows a two-dimensional layer structure, whereas compound 2 is a three-dimensional network composed of cd2+ and octa-dentate h2dtzpda2− via the tetrazole-n and the carboxylate group in a μ1,1,3-coo mode. the luminescence properties of hatzipa, h4dtzpda and the compounds were investigated at room temperature in the solid state.
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کلیدواژه
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crystal structure ,hatzipa/h4dtzpda ,cadmium ,luminescence
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آدرس
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guilin medical university, school of pharmacy, china. changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china, guilin medical university, school of pharmacy, china, changshu institute of technology, jiangsu laboratory of advanced functional material, department of chemistry and material engineering, china
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Authors
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