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metal–organic frameworks of cu2(tptc)-catalyzed cascade c–s coupling/csp2–h hydroxylation reaction
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نویسنده
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tian an-qi ,liu shan ,ren zhi-lin ,wang long ,li dong-sheng
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منبع
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journal of the iranian chemical society - 2020 - دوره : 17 - شماره : 6 - صفحه:1339 -1345
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چکیده
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This paper reports a novel disulfide-directed csp2–h hydroxylation cascade reaction strategy catalyzed by cu2(tptc), a metal–organic framework material with binuclear cu(ii) paddlewheel nodes. in the strategy, cu2(tptc) mof can effectively catalyze the coupling reaction of disulfide and arylboronic acid, and realize the disulfide-directed csp2–h hydroxylation reaction. this reaction proceeded well under cu2(tptc) mof catalyst with good yields, which provides an efficient method to the synthesis of functional organic molecules, such as 2-(phenylthio)phenols derivatives.
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کلیدواژه
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disulfide directed ,c–h hydroxylation ,cascade reaction ,metal–organic frameworks
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آدرس
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china three gorges university, college of materials and chemical engineering, key laboratory of inorganic nonmetallic crystalline and energy conversion materials, china, china three gorges university, college of materials and chemical engineering, key laboratory of inorganic nonmetallic crystalline and energy conversion materials, china, hubei university of arts and science, college of chemical engineering, china, china three gorges university, college of materials and chemical engineering, material analysis and testing center, key laboratory of inorganic nonmetallic crystalline and energy conversion materials, china, china three gorges university, college of materials and chemical engineering, key laboratory of inorganic nonmetallic crystalline and energy conversion materials, china
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Authors
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