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synthesis and characterization of novel polymeric organic–inorganic complex framework based on sodium 2,4-dioxo-6-aryl-3-oxa-bicyclo[3.1.0]hexane-1,5-dicarboxylate (sdaobdc) with three-dimensional hybrid networks
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نویسنده
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kashani elmira ,pesyan nader noroozi ,rashidnejad hamid ,marjani ahmad poursattar ,asl hooman yaghoobnejad
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منبع
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journal of the iranian chemical society - 2017 - دوره : 14 - شماره : 10 - صفحه:2143 -2156
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چکیده
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Synthesis and characterization of novel polymeric organic–inorganic complex based on sodium 2,4-dioxo-6-aryl-3-oxa-bicyclo[3,1,0]hexane-1,5-dicarboxylate with three-dimensional hybrid networks were reported. the polymeric complex was crystallizing in the triclinic, space group p1. as determined by x-ray single-crystal analysis, in this compound each na ion is coordinated by six o atoms: two from different carbonyl oxygen atom of carboxylic acid groups, two from bridged carbonyl oxygen atom of carboxylic acid groups, one from the carbonyl oxygen atom of cyclic anhydride and one from water molecule. the structure characterization was done by means of ir, 1h, 13c nmr, uv–vis spectroscopies, tg, flame photometry and x-ray crystallographic analysis.
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کلیدواژه
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polymeric organic–inorganic complex ,cyclopropane ,sodium hexa-coordinate polymer ,quasi-covalent h-bond ,mofs
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آدرس
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urmia university, faculty of chemistry, department of organic chemistry, iran, urmia university, faculty of chemistry, department of organic chemistry, iran, urmia university, faculty of chemistry, department of organic chemistry, iran, urmia university, faculty of chemistry, department of organic chemistry, iran, missouri university of science and technology, department of chemistry, usa
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Authors
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