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2d hydrogen-bonded manganese–picolinate coordination network: ionic liquid-induced synthesis, crystal structure and thermogravimetric analysis
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نویسنده
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siddiqui kafeel ahmad ,rajput swati singh ,lama prem
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منبع
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journal of the iranian chemical society - 2018 - دوره : 15 - شماره : 1 - صفحه:93 -99
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چکیده
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A new manganese coordination complex of formula [mn(2-picolinate)2·2h2o]·h2o based on 2-picolinic acid has been synthesized hydrothermally at 120 °c for 48 h in presence of ionic liquid tetraethylammonium hydroxide (25% methanolic solution). 1 crystallizes in monoclinic crystal system and is hydrogen-bonded metal-organic network in which aqua ligands are instrumental in deciding structural features. the reported complex 1 is insoluble in almost all organic solvents as well as in water and shows good thermal stability upto 450 °c.
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کلیدواژه
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crystal engineering ,hydrogen-bonded metal complexes ,ionic liquid-induced synthesis
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آدرس
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national institute of technology-raipur, department of chemistry, india, national institute of technology-raipur, department of chemistry, india, stellenbosch university, department of chemistry and polymer science, south africa
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Authors
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