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cyclopentene-fused [c60]-fullerenes: synthesis and electrochemical properties
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نویسنده
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sakhautdinov ilshat m. ,malikova rauilya n. ,biglova yulya n. ,khusnutdinov rail a. ,gumerov aynur m. ,khamitov edvard m. ,ivanov sergey p. ,yunusov marat s.
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منبع
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journal of the iranian chemical society - 2018 - دوره : 15 - شماره : 9 - صفحه:1975 -1985
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چکیده
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New cyclopentene-fused [c60]-fullerene derivatives containing terpene moieties have been synthesized by [3 + 2]-addition to fullerene c60. all obtained products were fully characterized by 1h- and 13c-nmr, ir, and ms. the electrochemical properties have been studied by cyclic voltammograms (cv), combined with absorption spectra, which are consistent with those obtained from density functional theory (dft) calculations. it was found that all fulleropyrrolidines showed very similar absorption spectra, orbital energies, in which electron densities in both the lumo and homo are mainly located on the fullerene cage, suggesting that c60 act as the acceptor. all the compounds exhibited good thermal stability. all determined characteristics of fullerene conjugates were compared to [6,6]-phenyl-c61-butyric acid methyl ester ([60]pcbm), a popular fullerene-containing compound.
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کلیدواژه
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cyclopentene-fused [c60]-fullerene derivatives ,allenoates ,phthalimide ,maleopimarimide ,phosphorus ylides ,electrochemistry ,density functional theory
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آدرس
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russian academy of sciences, ufa institute of chemistry, russian federation, russian academy of sciences, ufa institute of chemistry, russian federation, bashkir state university, department of chemistry, russian federation, russian academy of sciences, ufa institute of chemistry, russian federation, ufa state petroleum technological university, russian federation, bashkir state university, department of chemistry, russian federation, russian academy of sciences, ufa institute of chemistry, russian federation, russian academy of sciences, ufa institute of chemistry, russian federation
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Authors
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