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nickel-catalyzed denitrative etherification of activated nitrobenzenes
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نویسنده
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zamiran fatemeh ,ghaderi arash
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منبع
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journal of the iranian chemical society - 2019 - دوره : 16 - شماره : 2 - صفحه:293 -299
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چکیده
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Electron-deficient nitrobenzenes were coupled with phenols/alcohols to form diaryl/alkyl aryl ethers by the aid of nicl2 as the catalyst. the reactions were conducted under ligand- and oxidant-free conditions without the exclusion of air or moisture. the initial studies upon the mechanism of the reaction revealed two solvent-dependent approaches. in molten tbab, snar mechanism seems to be predominated, while, in dmf, the reaction might include the radical species.
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کلیدواژه
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denitrative etherification ,cross coupling ,nickel ,nitrobenzenes ,green conditions
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آدرس
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university of hormozgan, college of sciences, department of chemistry, iran, university of hormozgan, college of sciences, department of chemistry, iran
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Authors
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