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synthesis, characterization, hirshfeld surface analysis and theoretical calculation of new organic–inorganic hybrid material: (c4h7n2)6[as2w18o62]·4h2o
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نویسنده
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dhifi marwa ,thabet safa ,harchani ali ,haddad amor
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منبع
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journal of the iranian chemical society - 2019 - دوره : 16 - شماره : 4 - صفحه:777 -784
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چکیده
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New hybrid arsenotungstates based on dawson polyanions [c4h7n2]6[as2w18o62]·4h2o (1) have been isolated by conventional solution method and characterized by single-crystal x-ray diffraction, infrared spectrum and uv–visible spectroscopies and thermogravimetric analysis. hirshfeld surface analysis was performed to study the intermolecular interactions. compound 1 crystallizes in hexagonal system, in a p-3 space group, with cell parameters a = 20.2904(2) å, b = 20.2904(2) å, c = 16.8246(2) å, and a v = 5998.38(11) å3. compound 1 exhibits a three-dimensional chain constructed from well–dawson anions linked together with (c4h7n2)+ cations and water molecules.
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کلیدواژه
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arsenotungstates ,synthesis ,crystal structure ,characterizations ,hirshfeld surface
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آدرس
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university of tunis el manar, faculty of sciences of tunis, laboratory of materials, tunisia. university of monastir, faculty of sciences of monastir, tunisia, university of tunis el manar, faculty of sciences of tunis, laboratory of materials, tunisia. university of monastir, faculty of sciences of monastir, tunisia, university of tunis el manar, faculty of sciences of tunis, laboratory of materials, tunisia. university of monastir, faculty of sciences of monastir, tunisia, university of tunis el manar, faculty of sciences of tunis, laboratory of materials, tunisia. university of monastir, higher institute of applied sciences and technology mahdia, tunisia
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Authors
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