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synthesis, structure and optical properties of novel double penetration polypseudorotaxane compound templated by branched divalent cation template
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نویسنده
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wang fu-rong ,li su-min ,niu yun-yin ,hou hong-wei
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منبع
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journal of the iranian chemical society - 2019 - دوره : 16 - شماره : 5 - صفحه:939 -944
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چکیده
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This study is directed to branched cationic template, 1,3-bis(4-cyanopyridine) propane bromine salt (bcpyp·2br), which connected by metal pseudohalides to form novel double penetration polymeric compound: {(bcpyp)[cu2(scn)3.33·br0.68]·0.68h2o} (1). the structure was determined by single crystal x-ray diffraction analysis and further characterized by infrared spectra (ir), elemental analysis, powder x-ray diffraction (pxrd), and thermogravimetric (tg) analysis. compound 1 also shows the better photocatalysis ability of degrading methylene blue (mb) than degrading rhodamine(rhb) and methyl orange(mo) in water under 500 w xe vapor lamp irradiation.
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کلیدواژه
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3-bis(4-cyanopyridine) propane bromine salt ,double penetration polymer ,inorganic–organic hybrid ,photocatalysis
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آدرس
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zhengzhou university, college of chemistry and molecular engineering, china, zhengzhou university, college of chemistry and molecular engineering, china, zhengzhou university, college of chemistry and molecular engineering, china, zhengzhou university, college of chemistry and molecular engineering, china
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Authors
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