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solvent pre-treated effects of carbon nanotube-supported cobalt catalysts on activity and selectivity of fischer-tropsch synthesis
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نویسنده
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karimi ali ,mohajeri ali ,jebreili jolodar ali ,rashidi ali morad ,forsat khaled
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منبع
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journal of petroleum science and technology - 2016 - دوره : 6 - شماره : 1 - صفحه:14 -27
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چکیده
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In this study, the effect of preparation technique of carbon nanotube (cnt)-supported cobalt catalysts on the activity and selectivity of fischer-tropsch synthesis (fts) was studied. different concentrations of acetic acid were used for the pretreatment of the catalyst support to modify the surface properties of cnt. this modification improved the reduction degree and dispersion of supported cobalt simultaneously. the catalysts were prepared by incipient wetness impregnation of the cobalt precursor, and deionized water was used as the preparation medium. the obtained catalysts were characterized by xrd, tpr, tem, and h2 chemisorption. the catalysts prepared under the optimum conditions exhibited significant stability and activity for fts reaction in a cstr reactor during 120 hr of experimental tests.
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کلیدواژه
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carbon nanotube ,cobalt catalyst ,fischer–tropsch synthesis ,acetic acid ,functional groups
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آدرس
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research institute of petroleum industry (ripi), gas research division, iran, research institute of petroleum industry (ripi), gas research division, iran, research institute of petroleum industry (ripi), iran, research institute of petroleum industry (ripi), gas research division, iran, research institute of petroleum industry (ripi), gas research division, iran
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پست الکترونیکی
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forsatkh@ripi.ir
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Authors
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