stress corrosion cracking detection of sensitized stainless steel 304 in chloride media by using electrochemical impedance spectroscopy (eis)

Electrochemical impedance spectroscopy (eis) was used to detect stress corrosion cracking (scc)in stainless steel 304 alloy exposed to an aqueous environment at 120 °c. stainless steel 304 alloyas u-bend was tested in the solution that contains 40 weight percent of magnesium chloride. ubendedsamples were prepared according to astm g30. eis measurements were always performedsimultaneously on u-bend samples under stress and non-stress conditions. the results indicate thatchanges in phase shift versus time could be related to the stress corrosion cracking process. stresscorrosion cracking is detectable at a frequency of 23.95 hz. eis measurement can be used for sccmonitoring in u-bend samples. finally, analysis of the fracture surface by using metallographic andsem techniques confirmed the eis results