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Studying of Catalyst Deactivation in a Commercial Hydrocracking Process (ISOMAX)
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نویسنده
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Rashidzadeh M. ,Ahmad A. ,Sadighi S.
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منبع
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journal of petroleum science and technology - 2011 - دوره : 1 - شماره : 1 - صفحه:46 -54
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چکیده
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Catalyst deactivation as usually indispensable , although the rate which it occurs varies greatly . at first this article discusses the causes of deactivation in a commercial hydrocracking unit, called isomax. then , a 5-lump kinetic model including of catalyst decay function for hydrocracking of vacuum gas oil in a commercial plant is proposed. the model considers vacuum gas oil vgo having boiling poit higher than 380c , diesel 260-380c , kerosene 150-260c, naphta ibp-150c, and gas as products. by using selective catalyst decay function in the kinetic model the effect of the catalyst deactivation on the yield of products during time is studied . the prediction of the model during 1.5 years is in good agreement with the actual commercial data. the average absolute deviation aad% of the model for the strategic products like naphtha , kerosene and diesel are about 1.784% , 1.983% and 1.971% , respectively. also it is observed that the estimated parameters are consistent with the reported characteristics of amorphous catalysts
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کلیدواژه
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catalyst deactivation ,life model ,hydrocracking ,isomax
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آدرس
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Research Institute of Petroleum Industry, Catalysis Research Center, ایران, Universiti Teknologi Malaysia., Faculty of Chemical and Natural Resources Engineering, Malaysia, Research Institute of Petroleum Industry, Catalysis Research Center, ایران. Universiti Teknologi Malaysia, Faculty of Chemical and Natural Resources Engineering, Malaysia
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پست الکترونیکی
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rashidzadehm@ripi.ir
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Authors
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