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Corrosion inhibition of aluminum and aluminum silicon alloys in sodium hydroxide solutions by methyl cellulose
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نویسنده
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eid s. ,abdallah m. ,kamar e.m. ,el-etre a.y.
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منبع
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journal of materials and environmental science - 2015 - دوره : 6 - شماره : 3 - صفحه:892 -901
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چکیده
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Methyl cellulose was tested as inhibitor for corrosion of aluminum and aluminum silicon alloys in 0.1m naoh solution. the inhibition action of methyl cellulose was studied using potentiostatic polarization,electrochemical impedance spectroscopy (eis),cyclic voltammetry and potentiodynamic anodic polarization techniques. effect of temperature on the inhibition efficiency of studied and the values of activation thermodynamic parameters were calculated and explained. the inhibition efficiency increases with increasing the concentration of methyl cellulose and decreases with increasing temperature as well as si content. this was attributed to a lower affinity of the inhibitor to adsorb on si than on al. the inhibition action was explained on the basis of adsorption of methyl cellulose on the surface of al or al-si alloys forming a barrier of mass and charge transfer leading to protect the metal surface from the aggressive ions.
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کلیدواژه
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Adsorption; Aluminum; Aluminum silicon alloys; Corrosion inhibitors; Methyl cellulose
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آدرس
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chemistry department,faculty of science,benha university, Egypt, chemistry department,faculty of science,benha university, Egypt, chemistry department,faculty of science,benha university, Egypt, chemistry department,faculty of science,benha university, Egypt
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Authors
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