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Synthesis and electrical properties solid solution of the (1-x)BiO1.5-(x/4)Nb2Te2O9 (x=0.1,0.2) type δ-Bi2O3
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نویسنده
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loubbidi l. ,chagraoui a. ,villain s. ,bourja l. ,orayech b. ,ait sidi ahmed o. ,moussaoui a. ,tairi a.
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منبع
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journal of materials and environmental science - 2015 - دوره : 6 - شماره : 12 - صفحه:3517 -3523
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چکیده
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Polycrystalline samples of (1-x)bio1.5-(x/4)nb2te2o9 (x=0.1,0.2) type δ-bi2o3 were synthesized by a solid reaction and characterized by x ray diffraction. the electrical properties of this new phase were studied using electrical impedance spectroscopy in the temperature range from 200°c to 700°c. various impedance model including constant phase element and warburg impedances have been used to interpret the nyquist representations of electrical analyses. the electrical conductivity was determined to be 1.88165.10-3 scm-1 for x=0.1 and 1.14874.10-5 scm-1 for x=0.2 at the temperature 700°c. the activity energy determinate by arrhenius equation is 0.52ev and 0.48ev for x=0.1 and x=0.2 respectively.
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کلیدواژه
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Electrical impedance spectroscopy; Ionic conduction; Nyquist representations; δ-Bi2O3
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آدرس
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laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco, laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco, laboratoire im2np,avenue de l'université toulon var b.p 20132,bâtiment,la garde cedex, France, laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco, cic energigune,parque tecnológico,c/albert einstein,48, Spain, laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco, laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco, laboratoire de physico-chimie des matériaux appliqués (lpcma),faculté des sciences ben m'sik, Morocco
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Authors
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