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Synthesis,spectral and structural charcterization of novel dichloro-ruthenium(II)/triphenylphosphine/(3,4-diaminophenyl)(phenyl)methanone complex
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نویسنده
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warad i.
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منبع
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journal of materials and environmental science - 2013 - دوره : 4 - شماره : 5 - صفحه:822 -827
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چکیده
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The novel trans-[cl2ru(ii)(pph3)2(3,4-diaminophenyl)(phenyl)methanone] complex was obtained by reacting rucl2(pph3)3 with equimolar amounts of (3,4-diaminophenyl)(phenyl)methanone as diamine co-ligand in ch2cl2. one of the pph3 ligand was quantitatively exchanged by (3,4-diaminophenyl)(phenyl)methanone,even when excess diamine was added. the trans-rucl2 desired complex was characterized on the basis of elemental analysis,elemental analysis,fab-ms,ir,uv-vis,1h,13c and 31p{1h}nmr.
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کلیدواژه
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Diamine ligands; NMR; Phosphines; Ruthenium(II) complexes
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آدرس
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department of chemistry,an-najah national university, Palestine
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Authors
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