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A new route for the synthesis of symmetric and dissymmetric bis-triazol ligands and the catechol oxidase biomimetic catalytic activity of their copper(II) complexes
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نویسنده
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allali m. ,mouacha y. ,allali n. ,zarrouk a. ,habbadi n.
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منبع
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journal of materials and environmental science - 2016 - دوره : 7 - شماره : 8 - صفحه:3035 -3042
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چکیده
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An efficient route of synthesis of symmetric and dissymmetric [1,2,3]triazole-containing ligands via the easily accessible benzyl-protected alkylating synthon benzyl-4-bromomethyl-1h-1,2,3-triazole(1) is reported. the structure of l2 was confirmed by x-ray diffraction. first studies of the catalytic activity of their copper(ii) complexes suggest that these complexes could be proposed as catalyst for the oxidation of alcohols in carbonyl compounds or as artificial enzymes.
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کلیدواژه
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Catalytic activity; Diaza-crown ether; N ,N-diamine; [1 ,3]Triazole
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آدرس
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institut supérieur des professions infirmières et techniques de santé,ispits,de fès, Morocco, institut supérieur des professions infirmières et techniques de santé,ispits,de fès,morocco,laboratoire de chimie organique et d'agrochimie,université ibn tofail,faculté des sciences,kenitra, Morocco, laboratoire de chimie organique et d'agrochimie,université ibn tofail,faculté des sciences,kenitra, Morocco, lcae-urac 18,faculty of science,first mohammed university,po box 717,oujda, Morocco, laboratoire de chimie organique et d'agrochimie,université ibn tofail,faculté des sciences,kenitra, Morocco
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Authors
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