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   Experimental and theoretical studies for steel XC38 corrosion inhibition in 1 M HCl by N-(8-hydroxyquinolin-5-yl)-methyl)-N-phenylacetamide  
   
نویسنده el faydy m. ,galai m. ,touir r. ,el assyry a. ,ebn touhami m. ,benali b. ,lakhrissi b. ,zarrouk a.
منبع journal of materials and environmental science - 2016 - دوره : 7 - شماره : 4 - صفحه:1406 -1416
چکیده    In the present investigation,a new organic inhibitor,namely n-((8-hydroxyquinolin-5-yl) methyl)-nphenylacetamide (hqmp) was synthesized and characterized using 1h,13c nmr and ir spectroscopies. in the second time,the inhibition effect of hqmp on the steel xc38 corrosion in 1 m hcl,have been investigated using electrochemical measurements. the obtained results showed that the its inhibition efficiency increased with concentration and reached 93 % at 10-3 m. in addition,the hqmp takes its performance at the temperature range of 298-328 k. the adsorption of the inhibitor on the mild steel was well described by the langmuir isotherm. on the other hand,the establishing of correlation between the molecular structure of quantum chemistry indices was carried out using the density functional theory (dft).
کلیدواژه 8-Quinolinol; Acidic medium; Corrosion inhibition; DFT; N-phenylacetamide; Steel XC38; Synthesis
آدرس laboratoire d'agroressources,polymères et génie des procédés,département de chimie,université ibn tofail,b.p. 133,kénitra, Morocco, laboratoire d'ingénierie des matériaux et d'environnement: application et modelisation,département de chimie,université ibn tofail,b.p. 133,kénitra, Morocco, laboratoire d'ingénierie des matériaux et d'environnement: application et modelisation,département de chimie,université ibn tofail,b.p. 133,kénitra,morocco,centre régional des métiers de l'éducation et de la formation (crmef),avenue allal al fassi,madinat al irfane,bp 6210,rabat, Morocco, laboratoire d'optoelectronique et de physico-chimie des materiaux (unite associée au cnrst),département de physique,université ibn tofail,b.p. 133,kénitra, Morocco, laboratoire d'ingénierie des matériaux et d'environnement: application et modelisation,département de chimie,université ibn tofail,b.p. 133,kénitra, Morocco, laboratoire d'optoelectronique et de physico-chimie des materiaux (unite associée au cnrst),département de physique,université ibn tofail,b.p. 133,kénitra, Morocco, laboratoire d'agroressources,polymères et génie des procédés,département de chimie,université ibn tofail,b.p. 133,kénitra, Morocco, lc2ame,faculty of science,first mohammed university,po box 717,oujda, Morocco
 
     
   
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