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A study of 6-chloro-2-oxo-1,2-dihydroquinoline-4-carboxylic acid as new corrosion inhibitor for mild steel in hydrochloric acid solution
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نویسنده
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baba y.f. ,elmsellem h. ,rodi y.k. ,steli h. ,chahdi f.o. ,ouzidan y. ,sebbar n.k. ,essassi e.m. ,cherrak k.
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منبع
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journal of materials and environmental science - 2016 - دوره : 7 - شماره : 7 - صفحه:2424 -2434
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چکیده
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6-chloro-2-oxo-1,2-dihydroquinoline-4-carboxylic acid (p2) as a new corrosion inhibitor was synthesized in the present work. the corrosion inhibition of p2 in hydrochloric acid for mild steel was evaluated by potentiodynamic polarization measurements,electrochemical impedance spectroscopy,weight loss measurements,and dft. the results indicate that the p1 is mixed type inhibitor,and the adsorption of p2 on mild steel surface obeys langmuir isotherm. in addition,the inhibition efficiency increases with increasing the concentration of inhibitor and decreases with increasing the hydrochloric acid concentration. correlation between quantum chemical calculations and inhibition efficiency of the investigated compound is discussed using the density functional theory method (dft).
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کلیدواژه
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Corrosion; DFT; Electrochemical; Mild steel; P2; Weight loss
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آدرس
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laboratory of applied organic chemistry,faculty of science and technology,university sidi mohammed ben abdallah,fez, Morocco, laboratoire de chimie analytique appliquée,matériaux et environnement (lc2ame),faculté des sciences,b.p. 717,oujda, Morocco, laboratory of applied organic chemistry,faculty of science and technology,university sidi mohammed ben abdallah,fez, Morocco, laboratoire mécanique and oénergétique,faculté des sciences,université mohammed premier,oujda, Morocco, laboratory of applied organic chemistry,faculty of science and technology,university sidi mohammed ben abdallah,fez, Morocco, laboratory of applied organic chemistry,faculty of science and technology,university sidi mohammed ben abdallah,fez, Morocco, laboratoire de chimie organique hétérocyclique,urac 21,pôle de compétences pharmacochimie,mohammed v university,faculté des sciences,av. ibn battouta,rabat, Morocco, laboratoire de chimie organique hétérocyclique,urac 21,pôle de compétences pharmacochimie,mohammed v university,faculté des sciences,av. ibn battouta,rabat, Morocco, laboratoire de chimie analytique appliquée,matériaux et environnement (lc2ame),faculté des sciences,b.p. 717,oujda, Morocco
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Authors
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