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INVESTIGATING THE CORROSION BEHAVIOR OF NANO STRUCTURED COPPER STRIP PRODUCED BY ACCUMULATIVE ROLL BONDING (ARB) PROCESS IN ACIDIC CHLORIDE ENVIRONMENT
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نویسنده
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Nikfahm A. ,Danaee I. ,Ashrafi A. ,Toroghinejad M. R.
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منبع
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iranian journal of materials science and engineering - 2014 - دوره : 11 - شماره : 2 - صفحه:25 -36
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چکیده
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In this research accumulative roll bonding process as sever plastic deformation process was applied up to8 cycles to produce the ultrafine grain copper. microstructure of cycle 1, cycle 4 and cycle 8 investigated by temimages. by analyzing tem images the grain size measured below 100 nm in cycle 8 and it was with an average grainsize of 200 nm. corrosion resistance of rolled copper strips in comparing with unrolled copper strip was investigatedin acidic (ph=2) 3.5 wt. % nacl solution. potentiodynamic polarization and eis tests used for corrosion resistanceinvestigations. the corrosion morphologies analyzed by fe-sem microscopy after polarization test and immersion for40 hours. results show that the corrosion resistance decreased up to cycle 2 and increased after rolled for forth time.the corrosion degradation was more intergranular in cycle 2 and unrolled counterpart. it was more uniform ratherthan intergranular type in cycle 8. corrosion current density in unrolled sample (2.55 ?acm-2) was about two times ofthat in cycle 8 (1.45 ?acm-2). the higher corrosion rate in cycle 2 in comparison with others was attributed to unstablemicrostructure and increase in dislocation density whereas the uniform corrosion in cycle 8 was due to stable ufgformation.
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کلیدواژه
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Ultrafine Grain ,Corrosion ,Copper ,NaCl ,Accumulative Roll Bonding ,SPD
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آدرس
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petroleum university of technology, ایران, petroleum university of technology, ایران, shahid chamran university of ahvaz, ایران, isfahan university of technology, ایران
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Authors
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