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Using electrochemical impedance spectroscopy of salicylate anion selective electrode: simulation for behavior of electrode
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نویسنده
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MAZLOUM-ARDAKANI MOHAMMAD ,DEHGHAN MANSHADI ABDOLHOSEIN ,MOZAFFARI SAYED AHMAD ,AZIZI HADI
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منبع
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iranian journal of mathematical chemistry - 2013 - دوره : 4 - شماره : 1 - صفحه:41 -57
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چکیده
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In this paper, the behavior of the salicylate anion-selective electrode was studied using the electrochemical impedance spectroscopy technique. considering the diagram of the charge transfer resistance and -logarithm of the double layer capacitance versus -logarithm of the concentration, linear range concentration increased to 1.0×10-8-1.0×10-1 m and 1.0×10-9-1.0×10-1 m, respectively. among the other characteristics of this study, it can be pointed out a wide ph range of 4.0-10.0. then one-impedance for one-concentration method was used to measure the salicylate ion at the linear range of 1.0×10-8-1.0×10-1 m. finally, the impedance spectra of this electrode were simulated in which the obtained results of this simulation indicate proximity of experimental and simulation data.
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کلیدواژه
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Salicylate ,Anion-selective electrode ,Electrochemical impedance spectroscopy ,Simulation
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آدرس
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yazd university, ایران, payame noor university, ایران, Department of Chemical Technologies; Iranian Research Organization for Science & Technology (IROST), P.O. Box 15815-3538, Tehran, I. R. of Iran, ایران, Depatment of Mathematics, Taft Branch, Islamic Azad University, Taft, I. R. of Iran, ایران
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Authors
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