The Electrochemical Behavior of AISI 321 Stainless Steel in Alkaline Media

In this paper, the electrochemical behaviour of passive films formed on aisi 321 stainless steel (aisi 321)immersed in 0.1 m naoh + 0.1 m koh solution was evaluated by different electrochemical techniques. forthis purpose, passive films were formed at open circuit potential for 1 to 12 hours and then electrochemicalmeasurements were done. the polarization curves suggested that aisi 321 showed excellent passive behaviourin 0.1 m naoh + 0.1 m koh solution. mott–schottky analysis indicated that the accepted densities were in therange of 1021 cm-3 and decreased with immersion time. electrochemical impedance spectroscopy (eis) resultsshowed that the best electrical equivalent circuit presented two time constants: the high-medium frequencies timeconstant could be correlated with the charge transfer process and the low frequencies time constant was associatedwith redox processes taking place in the surface film. also, eis results showed that polarization resistance wasincreased with formation time from 1 until 12 hours, due to the thickening of passive film.