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modeling and optimization: isomerization reaction rate using response surface methodology with two kinetic model over bi-porous catalysts
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نویسنده
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parsafard nastaran
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منبع
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journal of chemical and petroleum engineering - 2024 - دوره : 58 - شماره : 1 - صفحه:1 -15
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چکیده
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A response surface methodology (rsm) with 3 levels and 4 variables was used to model and optimize the n-heptane isomerization kinetic process over pt-hzsm-5/hms catalysts in a fixed bed micro reactor. 30 sets of isomerization rate tests were performed at different conditions of h2 flow rate (20-45 ccmin−1), n-heptane flow rate (2-4.5 cch−1), the temperatures (200-350 °c), and the weight percent of hzsm-5 (10-40%). it was observed that the amounts of hzsm-5 into pt-hms structure has the greatest effect on the rate of reaction. the surface and contour plots confirm that the rates do not considerably change versus temperature, n-heptane and h2 flow rates. 0.24 molg−1s−1 is the highest reaction rate obtained in the 4.5 cch−1 n-heptane and 45 cc min−1 h2 flow rate. the rsm was effective for predicting and optimizing this process. the modelling results also show both power-law and langmuir–hinshelwood models are in agreement with the experimental data.
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کلیدواژه
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kinetics ,langmuir–hinshelwood model ,n-heptane isomerization ,rsm-ccd
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آدرس
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kosar university of bojnord, department of applied chemistry, iran
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پست الکترونیکی
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n-parsafard@kub.ac.ir
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Authors
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