The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2((mu)-dicyd)](PF6)2
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نویسنده
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Rezvani AliReza ,Hadadzadeh Hassan
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منبع
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iranian journal of chemistry and chemical engineering - 2005 - دوره : 24 - شماره : 2 - صفحه:€17 -20
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چکیده
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Electrochemical behavior of the new mono and dinuclear co (iii) complexes of the types trans-fpyco((do)(doh)pn )(l)]pf6 and [{py co((do)(doh)pn)}2 ((mu)-dicyd)] (pf6)2 have been studied in acetonitrile solution. all the mono nuclear complexes show two quasi- reversible reduction couples associate to co(iii/ii)and co(ii/i). each of these redox couples split to two one electron waves in dinuclear complex.
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کلیدواژه
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Phenycyanamide ,Co(III) complex ,Compropordonation equilibrium constant ,Oxime.
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آدرس
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university of sistan and baluchestan, ایران, university of sistan and baluchestan, ایران
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پست الکترونیکی
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ali@hamoon. usb. ac. ir
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