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   Raising Distillate Selectivity and Catalyst Life Time in Fischer-Tropsch Synthesis by Using a Novel Dual-Bed Reactor  
   
نویسنده Tavasoli Ahmad ,Sadaghiani Kambiz ,Khodadadi Abbas Ali ,Mortazavi Yadollah
منبع iranian journal of chemistry and chemical engineering - 2007 - دوره : 26 - شماره : 2 - صفحه:109 -117
چکیده    In a novel dual bed reactor fischer-tropsch synthesis was studied by using two diffrent cobalt catalysts. an alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a rutenuim promoted cobalt catalyst in the second bed. the activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed reactor system. the methane selectivity in the dual-bed reactor was about 18.9 % less compared to that of the single-bed reactor. the c5+ selectivity for the dual-bed reactor was 10.9 % higher than that of the single-bed reactor. accelerated deactivation of the catalysts in the dual-bed reactor was 42 % lower than that of the single-bed reactor. it was revealed that the amount of catalysts activity recovery after regeneration at 400 °c in the dual-bed system is higher than that of the single-bed system.
کلیدواژه Fischer-Tropsch ,Cobalt catalyst ,Dual-bed ,Selectivity ,Life time
آدرس Research Institute of Petroleum Industry (RIPI), I. R. IRAN, Research Institute of Petroleum Industry (RIPI), I. R. IRAN, university of tehran, Department of Chemical Engineering, ایران, university of tehran, Department of Chemical Engineering, ایران
پست الکترونیکی tavassolia@ripi.ir
 
     
   
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