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advanced mwcnt-cooh@zno nano catalyst for biodiesel production from used cooking oil enhancing fuel quality and reducing engine wear
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نویسنده
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al-ani younis muhsin younis ,ahmadlouydarab majid
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منبع
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iranian journal of chemistry and chemical engineering - 2025 - دوره : 44 - شماره : 7 - صفحه:1757 -1776
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چکیده
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In response to the rising global demand for renewable energy solutions, biodiesel has emerged as an excellent ecological alternative to fossil fuels. this study aims to develop and evaluate mwcnt-cooh@zno, a novel nanocatalyst synthesized by functionalizing multiwalled carbon nanotubes (mwcnts) with zno2 to produce high-quality biodiesel from waste cooking oil. optimal reaction parameters (70 °c, 30 minutes, 600 rpm, oil-to-methanol ratio of 1:8, and 400 mg catalyst) were determined using the taguchi method. under these conditions, a yield of 96.3% of biodiesel was obtained. the mwcnt-cooh@zno nanocatalyst enabled biodiesel synthesis that met astm d6751 standards for a flash point of 146 °c, a viscosity of 3.8 mm²/s, a density of 872 kg/m³ at 16 °c, a pour point of -1 °c, and a cloud point of -2 °c. the mwcnt-cooh@zno nanocatalyst demonstrated 89% recyclability after three cycles and reduced friction and wear rates by up to 15% under extreme pressure. this study establishes mwcnt-cooh@zno as a scalable nanocatalyst for sustainable biodiesel production, offering improved environmental friendliness and engine protection.
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کلیدواژه
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biodiesel synthesis ,nanocatalyst ,wear resistance ,catalytic efficiency ,renewable energy
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آدرس
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middle technical university, technical engineering college-baghdad, iraq. university of tabriz, faculty of chemical and petroleum engineering, iran, university of tabriz, faculty of chemical and petroleum engineering, iran
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پست الکترونیکی
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mahmadlouydarab@tabrizu.ac.ir
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Authors
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