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surface chemistry and catalysis: understanding interfaces for enhanced reactivity
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نویسنده
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minaie elnaz ,jalali somayeh ,amiri prshang ,ghafourifard farhad ,gheshlaghi esmaeil
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منبع
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iranian journal of chemistry and chemical engineering - 2024 - دوره : 43 - شماره : 5 - صفحه:0725 -0738
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چکیده
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Catalysis stands as a cornerstone of modern chemical processes, shaping industries from energy to pharmaceuticals. this review embarks on a comprehensive journey through the intricate interplay between surface chemistry and catalytic reactivity. employing a rigorous methodology involving literature from scopus, web of science, and google scholar, the study explores key topics. surface chemistry takes center stage, delving into the principles of adsorption and desorption on catalytic surfaces, guided by forces like van der waals and electrostatic interactions. surface reaction mechanisms unveil how surface arrangements drive reaction pathways and selectivity. catalyst-substrate interactions underscore the synergy between active sites, coordination chemistry, and binding energies. comparing heterogeneous and homogeneous catalysis reveals distinct advantages and challenges for each approach. nanocatalysis unveils how nanoparticle size and morphology revolutionize reactivity, with implications spanning environmental sustainability to energy conversion. catalyst design strategies, encompassing surface area optimization and hierarchical structures, enrich the toolkit. characterization techniques, from x-ray spectroscopy to electron microscopy, lay bare structural intricacies. real-world industrial applications illustrate catalysis’s impact across petrochemicals, pharmaceuticals, and environmental remediation. challenges of catalyst stability, transient intermediates, and complex multi-step reactions underscore the evolving landscape. the conclusion highlights the potential of catalysis to address global challenges. with innovative techniques and collaborative efforts, catalytic science charts a course towards a sustainable future, poised to tackle society’s most pressing issues.
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کلیدواژه
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catalysis ,surface chemistry ,adsorption ,reaction mechanisms ,catalyst design ,nanocatalysis
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آدرس
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azarbaijan shahid madani university, electroanalytical chemistry laboratory, department of chemistry, iran, urmia university of medical sciences, cellular & molecular research center, iran, university of kurdistan, faculty of physics, iran, tarbiat modares university, department of mineral processing, iran, amirkabir university of technology, department of chemical engineering, iran
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پست الکترونیکی
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efarmani@aut.ac.ir, efarmaplsm@gmail.com
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Authors
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