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wastewater treatment by new high-performance activated carbon from semecarpus anacardium and quercus infectoria nutshells: applications- kinetic and equilibrium studies
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نویسنده
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ghasemzadeh naser ,ghadiri mohammad ,behroozsarand ali reza ,seifali abbas abadi mehrdad
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منبع
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iranian journal of chemistry and chemical engineering - 2024 - دوره : 43 - شماره : 7 - صفحه:2737 -2749
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چکیده
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This study utilized semecarpus anacardium (sa) and quercus infectoria (qi) nutshells as raw materials to manufacture activated carbon (ac) which is both inexpensive and possesses a large surface area. all materials were examined using fourier transform infrared (ft-ir) spectroscopy, scanning electron microscopy (sem/edx), x-ray powder diffraction (xrd), and brunauer, emmett, and teller (bet) surface area methods. the effective synthesis of ac was validated by surface functional groups in ft-ir spectra and xrd diffractograms, which showed a broad peak in the region of 2θ=15-28° and a faint and wide peak in the range of 2θ=40-48°. the bet results indicated that the ac synthesized from sa and activated with koh (acsak) had the greatest surface area (717 m2/g), the most enormous pore volume (0.286 cm3/g), and mean pore diameters (<2nm). the synthesized ac in this research can be classified into micro-pore adsorbents entirely. finally, the resulting acsak was applied to methylene blue (mb) adsorption. adsorption studies demonstrate that the langmuir isotherm (r2=0.996) matches somewhat more accurately than the freundlich and temkin isotherms. our adsorption kinetics findings show that the pseudo-second-order model has the maximum fitness and accuracy on mb adsorption data in ac (r2 = 0.999).
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کلیدواژه
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activated carbon ,semecarpus anacardium ,quercus infectoria ,methylene blue ,isotherms ,kinetics
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آدرس
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urmia university of technology, faculty of renewable energies, department of chemical engineering, iran, urmia university of technology, faculty of renewable energies, department of chemistry, iran, urmia university of technology, faculty of renewable energies, department of chemical engineering, iran, iran polymer and petrochemical institute (ippi), polymerization engineering department, iran
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پست الکترونیکی
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m.seyfali@ippi.ac.ir
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Authors
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