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synthesis of schiff base-functionalized fullerene anchored palladium complex as a recyclable nanocatalyst in the heck reaction and oxidation of alcohols
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نویسنده
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noroozi mohammad ,ghahri saremi shokoufeh
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منبع
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iranian journal of chemistry and chemical engineering - 2021 - دوره : 40 - شماره : 5 - صفحه:1395 -1405
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چکیده
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The use of nanocarbon support materials such as fullerene (c60) helps the dispersion of catalysts and creates a new method to develop nanomaterials as a result of its garbled structure pd-supported on schiff base modified fullerene (c60lpd^2+ and c60lpd^0) were fabricated. the obtained catalysts were characterized by ft-ir, xrd, tem, tga, and icp. to investigate the catalytic properties, this catalyst was used in aerobic oxidation of alcohols and heck coupling as model reactions. the results showed that the efficiency of catalysts has about 75% to 92% and 90% to 98% in these two reactions, respectively. the catalyst can be rapidly readily regained and reused at least 5 consecutive cycles without notable leaching and loss of its catalytic actuality
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کلیدواژه
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polyamine-functionalized c60; nanocatalyst; oxidation of alcohol
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آدرس
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research institute of petroleum industry (ripi), kermanshah center, iran, payame noor university, department of chemistry, iran
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پست الکترونیکی
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sho.saremi@gmail.com
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Authors
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