|
|
synthesis of n-cnt-tio2 nanocatalyst: application in direct oxidation of h2s to sulfur
|
|
|
|
|
نویسنده
|
daraee maryam ,baniadam majid ,rashidi ali morad ,maghrebi morteza
|
منبع
|
iranian journal of chemistry and chemical engineering - 2020 - دوره : 39 - شماره : 5 - صفحه:131 -144
|
چکیده
|
In this study, nitrogen-doped mwcnt-tio2 nanocatalyst (n-cnt-tio2) with 1, 3, and 5 wt. % nitrogen has been synthesized and its catalytic activity in the oxidation of h2s to sulfur has been studied at a temperature of 200°c and o2/h2s mole ratio of 0.5 and compared with those of neat tio2 and tio2-cnt hybrid. their structure, morphology, and chemical properties have been determined by n2 adsorption-desorption isotherms, xrd, sem, tem, uv, and ft-ir. n-cnt-tio2 exhibited improved performance compared with tio2-cnt due to the presence of nitrogen groups. in addition, the nanocatalyst was comparable (up to 5%) with tio2 because of the presence of a lower bandgap and synergistic effects. furthermore, 5%n-cnt-tio2 has shown the highest catalytic activity among n-cnt-tio2 nanocatalysts due to its higher surface area and pore volume.
|
کلیدواژه
|
n-cnt-tio2; nanocatalyst; nitrogen group; catalytic activity
|
آدرس
|
ferdowsi university of mashhad, faculty of engineering, chemical engineering department, iran, ferdowsi university of mashhad, faculty of engineering, chemical engineering department, iran, research institute of petroleum industry (ripi), nanotechnology research center, iran, ferdowsi university of mashhad, faculty of engineering, chemical engineering department, iran
|
پست الکترونیکی
|
mmaghrebi@um.ac.ir
|
|
|
|
|
|
|
|
|
|
|
|
Authors
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|