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   molybdenum-schiff base complex immobilized on magnetite nanoparticles as a reusable epoxidation catalyst  
   
نویسنده masteri-farahani majid ,taghizadeh fereshteh
منبع iranian journal of chemistry and chemical engineering - 2018 - دوره : 37 - شماره : 6 - صفحه:35 -42
چکیده    The surface of magnetite nanoparticles as nano-sized solid support was modified with a molybdenum-schiff base complex to prepare an easily separable heterogeneous catalyst for the epoxidation of olefins. characterization techniques such as fourier transform infrared and inductively coupled plasma optical emission spectroscopies, x-ray diffraction, vibrating sample magnetometry, scanning, and transmission electron microscopies indicated the presence of molybdenum- schiff base complex and a magnetite core in the catalyst. the magnetite nanoparticles supported mo catalyst exhibited high catalytic activity and selectivity toward the epoxidation of olefins and was easily recovered from the reaction mixture by magnetic separation to be utilized for subsequent reactions. the catalyst showed reusability for three times without significant loss of activity.
کلیدواژه magnetite ,molybdenum ,recoverable ,catalyst ,epoxidation
آدرس kharazmi university, faculty of chemistry, iran, islamic azad university, ardabil branch, faculty of chemistry, iran
پست الکترونیکی taghizadeh@yahoo.com
 
     
   
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