پراکندگی و توزیع ژئوشیمیایی عناصر کمیاب و کانساری در کانسار رگه‌ ای چاه‌ مسی، شمال شهربابک

کانسار رگه‌ای چندفلزی چاه‌‌مسی در کمربند مس کرمان و مجموعه ماگمایی ارومیه‌دختر واقع‌شده است. در این محدوده، سنگ‌های میزبان شامل سنگ‌های آتشفشانی و آذرآواری است که به‌ شدت تحت‌تاثیر دگرسانی گرمابی پروپیلیتیک با چیرگی کربنات‌کلریت قرار گرفته‌اند. کانی‌های پیریت، کالکوپیریت، گالن و اسفالریت، سولفیدهای اصلی در ذخیره چاه‌مسی هستند که با دگرسانی سیلیسی و رسی همراه می‌شوند. همچنین در بخش سوپرژن و زون اکسیدان، کالکوسیت، مالاکیت، کوولیت، آزوریت و اکسیدها و هیدروکسیدهای آهن دیده می‌شود. در بررسی ضرایب همبستگی عناصر به روش پیرسون، بیشترین میزان ضریب همبستگی مربوط به عناصر pbzn و agau با میزان بیشتر از 7/0 است و در درجه بعدی اهمیت زوج عناصر cuag، cufe، cuau و feag با میزان ضریب همبستگی بیشتر از 6/0 قرار می‌گیرند؛ در‌حالی‌که همبستگی عنصر mo با دیگر عناصر ضعیف است. تحلیل خوشه‌ای نیز نتایج مشابهی به‌دست می‌دهد. به‎نظر می رسد، فراوانی رگه ‌های حاوی کانه ‌زایی عناصر فلزی سرب، روی و طلا اغلب در ترازهای سطحی‌ تر رخ‌داده است؛ درحالی‌که رگه‌ های حاوی کانه ‌زایی مس و نقره، علاوه‌بر ترازهای سطحی، در ترازهای عمقی ‌تر نیز دارای تمرکزهای قابل‌توجهی هستند. این یافته‌ها بیانگر احتمال وجود عیار‌های قابل‌قبول در عمق بیشتر کانسار چاه‌مسی و در نتیجه الزام ادامه عملیات حفاری است. عیار بالای عنصر مولیبدن در ترازهای سطحی به نظر می‌تواند به‌علت هم‌پوشانی هاله‌های ژئوشیمیایی اولیه رگه‌های مختلف و یا تاثیر میزان پیریت، درجه ph و درجه قلیائیت سیال بوده باشد.

Dispersion and distribution of trace and ore elements in the polymetalic vein- type Chah-Mesi ore deposit, north of Shahre-Babak

Introduction The ChahMesi polymetallic veintype ore deposit, located 40 km north of ShahreBabak city and 1.5 km southwest of Miduk porphyry copper deposit, is situated in the DehajSarduieh belt as a part of the Urumieh–Dokhtar magmatic Arc  (UDMA) (Figure 1). The main objectives of this research study are to investigate: (1) characterization of multielement distribution associated with Cu mineralization, in order to demonstrate prediction of elemental concentration applied to identify highgrade ore bodies, (2) evaluating the interrelationships between copper, molybdenum, iron, led, zinc, gold and silver.   Materials and methods Petrography and mineralography of the ChahMesi ore deposit were carried out using thin and polished sections. More than 980 chemical analyses of samples collected from 35 boreholes of the National Iranian Copper Industry Company (NICICO) were implemented to evaluate the statistical as well as spatial distribution and dispersion of multielement halos. Geochemical data processing was performed by applying Excel (2010), SPSS (19), Datamine (Studio3.22.84.0) and Surfer10 (2011) software packages.   Results The ChahMesi ore deposit consists of four main and some minor polymetalic (CuPbZnAg) quartzsulfide veins, with NESW and NS trending and 6580 degree dipping, which intersected the Eocene volcanic and pyroclastic sequences (Figure 2). It seems that mineralization has mainly occurred along these quartzsulfide veins overlaid by Quaternary alluvium. Based on rock outcrops, the prominent mineralization has been controlled by structural features including faults and fractures that provided proper conditions for reaction of hydrothermal fluids with the host rocks. In the ChahMesi ore deposit, silicified veins containing polymetallic mineralization have predominantly occurred along the main faults and shear zones. The intensity of argillic alteration dramatically decreases outward from the mineralized quartz veins (Figure 3). Propylitic alteration which is composed of calcite and chlorite minerals has extended in the peripheral zones and does not represent a clear relationship with Cu mineralization. The main host rocks in the ChahMesi ore deposit consist of basalt to basaltic andesite, with porphyry to glomeroporphyry textures, and to a lesser extent of pyroclastic rocks (Figure 4). The ore bodies are mainly composed of pyrite, chalcopyrite, sphalerite and galena. The ore minerals are accompanied with chalcocite, malachite, covellite, azurite and iron hydroxides that have been formed during supergene and weathering processes (Figure 5). According to field surveys, structural controls have played an important role in the mineralization of the ChahMesi ore deposit. Discussion Geochemical investigation in the ChahMesi ore deposit, using Pearson correlation coefficient of trace elements (Table 1), indicated the highest correlation coefficient (more than 0.7) between PbZn and AgAu elements, due to their similar geochemical affinities during epigenetic mineralization. Other significant correlations were observed between CuAg, CuFe, CuAu and FeAg with a correlation coefficient of more than 0.6; while the Mo shows weak correlation with other elements.  Based on cluster analysis, the trace elements that are associated with mineralization can be classified into four main clusters of PbZn, Mo, CuFeAg and Au (Figure 6). Noteworthy, despite the fact that Mo and Au each separately form their individual clusters, Au still shows some proximities with the CuFeAg cluster that indicate their genetic relationship. However, Mo displays the most dissimilarity with other clusters, which indicates the role of different processes in its distribution. The results of this analysis are well in line with correlation coefficients. The geochemical vertical zonality of trace elements in the ChahMesi ore deposit were studied using four borehole data from different parts of the ore deposit (Figures 7 and 8). This demonstrated that variation of elements at different depths does not follow a uniform pattern due to differences in the type and amount of ore minerals in the veins. The veins containing lead, zinc and gold mineralization are highly abundant at the shallower levels based on geochemical maps of the ChahMesi ore deposit (Figure 9). In contrast, the veins containing copper and silver mineralization have been considerably developed in both shallow and deeper levels. The high degree of Mo at shallow levels seems to occur due to either superimposition of primary geochemical haloes of various veins (Li et al., 1995, 2016) and/or the effect of amount of pyrite, pH, and alkalinity contents of hydrothermal fluids (Leanderson et al., 1987). The average value of different elements in intervals of 50 meters from the shallow (2500 meters) to the deep (2300 meters) levels are determined by existence of maximum abundance of lead, zinc and gold elements at surface levels. However, the highest average abundance of copper occurs in the deepest level. The highest average value of silver is also located in the 2450, 2350, and 2500 meters levels, which is economically valuable (Table 2). Therefore, the continuation of drilling in the southern part of the ChahMesi ore deposit into deeper levels is strongly recommended as there may still exist more concentrations of copper and silver there.   Acknowledgment The authors are grateful to the honorable personnel of the Miduk Copper Mine for their efforts in providing field studies and access to geochemical analyses.   References Leanderson, P.J., Schrader, E.L., Brake, S. and Kaback, D.S., 1987. Behavior of molybdenum during weathering of the Ceresco Ridge porphyry molybdenite deposit, Climax, Colorado and a comparison with the Hollister deposit, North Carolina. Applied Geochemistry, 2‌(4): 399–415. Li, H., Wang, Z.N. and Li, F.G., 1995. Ideal models of superimposed primary halos in hydrothermal gold deposits. Journal of Geochemical Exploration, 55‌(1–3): 329–336. Li, Y., Zhang, D., Dai, L., Wan, G. and Hou, B., 2016. Characteristics of structurally superimposed geochemical haloes at the polymetallic Xiasai silverleadzinc ore deposit in Sichuan Province, SW China. Journal of Geochemical Exploration, 169: 100–122.