Cross-Aldol condensation of isobutyraldehyde and formaldehyde using phase transfer catalyst
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نویسنده
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hashmi a.
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منبع
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journal of saudi chemical society - 2016 - دوره : 20 - شماره : Supplement 1 - صفحه:S382 -S386
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چکیده
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The hydroxypivaldehyde (hpa) precursor intermediate for the synthesis of neopentyl glycol (npg) is prepared by novel cross aldol condensation of isobutyraldehyde and formaldehyde at 20 °c using benzyltrimethylammonium hydroxide,a basic phase transfer catalyst. a feed mole ratio of 1.1:1.0:0.04 (isobutyraldehyde:formaldehyde:benzyltrimethylammonium hydroxide) afforded hydroxypivaldehyde as white solid in almost quantitative yield with ∼100% selectivity.[formula omited] © 2013
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کلیدواژه
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Benzyltrimethylammonium hydroxide; Hydroxypivaldehyde; Neopentyl glycol
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آدرس
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saudi basic industries corporation (sabic),p.o. box 42503, Saudi Arabia
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