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   REMOVAL OF GLYCEROL FROM PALM OIL-BASED BIODIESEL USING NEW IONIC LIQUIDS ANALOGUES  
   
نویسنده HO K. C. ,SHAHBAZ K. ,RASHMI W. ,MJALLI F. S. ,HASHIM M. A. ,ALNASHEF I. M.
منبع journal of engineering science and technology - 2015 - دوره : 10 - شماره : Special Issue 1 - صفحه:98 -111
چکیده    Upon the completion of the transesterification reaction, the produced biodiesel has to be purified from the by-product glycerol before being employed as a potential diesel substitute. the glycerol content must meet the limit set by the international biodiesel standards; namely en 14214 and astm d6751. the conventional purification methods such as water washing, dry washing and membrane separation are prone to significant product loss, environmental pollution and increased production cost. in this work, seven new ternary deep eutectic solvents (dess) were synthesised from choline chloride (chcl) salt and two glycols-based hydrogen bond donors, namely glycerol and ethylene glycol. these dess were employed as extraction solvents to remove total glycerol from palm oil-based biodiesel. the results revealed that the synthesised dess have a higher total glycerol removal efficiency than that of free glycerol. complete removal of free and total glycerol was attained by des 3 at a molar ratio of 0.5:1 (des 3: biodiesel).
کلیدواژه Eutectic ,Biodiesel ,Glycerol ,Removal ,Palm Oil ,ethylene glycol.
آدرس Taylor’s University, School of Engineering, Malaysia, Taylor’s University, School of Engineering, Malaysia, Taylor’s University, School of Engineering, Malaysia, Sultan Qaboos University, Department of Petroleum and Chemical Engineering, Oman, university of malaya, Department of Chemical Engineering, Malaysia, Masdar Institute for Science and Technology, Department of Chemical and Environmental Engineering, United Arab Emirates
 
     
   
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